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Версия для печати | Главная > Институт > Структура Института > Отдел физико-химических методов исследования > Группа ЯМР спектроскопии каталитических превращений углеводородов > Ключевые публикации

Ключевые публикации

ВАЖНО! Все публикации сотрудников Института Вы можете найти здесь:
Система мониторинга и учета научной деятельности ИК СО РАН SciAct


  1. Kolokolov, D. I.; Stepanov, A. G.; Guillerm, V.; Serre, C.; Frick, B.; Jobic, H., Probing the Dynamics of the Porous Zr Terephthalate UiO-66 Framework Using 2H NMR and Neutron Scattering. J. Phys. Chem. C 2012, 116, 12131−12136.

  2. Kolokolov, D. I.; Kazantsev, M. S.; Luzgin, M. V.; Jobic, H.; Stepanov, A. G., Direct 2H NMR Observation of the Proton Mobility of the Acidic Sites of Anhydrous 12-Tungstophosphoric Acid. ChemPhysChem 2013, 14, 1783−1786.

  3. Kolokolov, D. I.; Jobic, H.; Stepanov, A. G.; Guillerm, V.; Devic, T.; Serre, C.; Férey, G., Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy. Angew. Chem. Int. Edit. 2010, 49, 4791−4794.

  4. Kolokolov, D. I.; Diestel, L.; Caro, J.; Freude, D.; Stepanov, A. G., Rotational and Translational Motion of Benzene in ZIF-8 Studied by 2H  NMR: Estimation of Microscopic Self-Diffusivity and Its Comparison with Macroscopic Measurements. J.  Phys. Chem. C 2014, 118, 12873−12879.

  5. Nishchenko, A. M.; Kolokolov, D. I.; Stepanov, A. G., Mobility of Solid tert-Butyl Alcohol Studied by Deuterium NMR. J. Phys. Chem. A 2011, 115, 7428−7436.

  6. Kolokolov, D. I.; Kazantsev, M. S.; Luzgin, M. V.; Jobic, H.; Stepanov, A. G., Characterization and Dynamics of the Different Protonic Species in Hydrated 12-Tungstophosphoric Acid Studied by 2H NMR. J. Phys. Chem. C 2014, 118, 30023−30033.

  7. Kolokolov, D. I.; Stepanov, A. G.; Jobic, H., Mobility of the 2-Methylimidazolate Linkers in ZIF-8 Probed by 2H NMR: Saloon Doors for the Guests. J. Phys. Chem. C 2015, 119, 27512-27520.

  8. Kolokolov, D. I.; Glaznev, I. S.; Aristov, Y. I.; Stepanov, A. G.; Jobic, H., Water Dynamics in Bulk and Dispersed in Silica CaCl2 Hydrates Studied by 2H NMR. J. Phys. Chem. C 2008, 112, 12853−12860.

  9. Arzumanov, S. S.; Stepanov, A. G., Parahydrogen-Induced Polarization Detected with Continuous Flow Magic Angle Spinning NMR. J. Phys. Chem. C 2013, 117, 2888-2892.

  10. Stepanov, A. G., Basics of Solid-State NMR for Application in Zeolite Science: Material and Reaction Characterization. In Zeolites and Zeolite-like Materials, Sels, B. F.; Kustov, L. M., Eds. Elsevier Inc.: 2016; p. 137–188.

  11. Gabrienko, A. A.; Danilova, I. G.; Arzumanov, S. S.; Toktarev, A. V.; Freude, D.; Stepanov, A. G., Strong Acidity of Silanol Groups of Zeolite Beta: Evidence from the Studies by IR Spectroscopy of Adsorbed CO and 1H  MAS NMR. Microporous Mesoporous Mat. 2010, 131, 210–216.

  12. Luzgin, M. V.; Freude, D.; Haase, J.; Stepanov, A. G., Methane Interaction with Zn2+-Exchanged Zeolite H-ZSM-5: Study of Adsorption and Mobility by One- and Two-Dimensional Variable-Temperature 1H Solid-State NMR. J. Phys. Chem. C 2015, 119, 14255–14261.

  13. Stepanov, A. G.; Arzumanov, S. S.; Gabrienko, A. A.; Toktarev, A. V.; Parmon, V. N.; Freude, D., Zn-Promoted Hydrogen Exchange for Methane and Ethane on Zn/H-BEA Zeolite. In situ 1H MAS NMR Kinetic Study. J. Catal. 2008, 253, 11–21.

  14. Arzumanov, S. S.; Reshetnikov, S. I.; Stepanov, A. G.; Parmon, V. N.; Freude, D., In situ 1H and 13C MAS NMR Kinetic Study of the Mechanism of H/D Exchange for Propane on Zeolite HZSM-5. J. Phys. Chem. B 2005, 109, 19748–19757.

  15. Stepanov, A. G.; Arzumanov, S. S.; Ernst, H.; Freude, D., 1H MAS NMR Monitoring of the 13C-Labeled Carbon Scrambling for Propane in Zeolite H-ZSM-5. Chem. Phys. Lett. 2006, 420, 574–576.

  16. Gabrienko, A. A.; Arzumanov, S. S.; Moroz, I. B.; Toktarev, A. V.; Wang, W.; Stepanov, A. G., Methane Activation and Transformation on Ag/H-ZSM-5 Zeolite Studied with Solid-State NMR. J. Phys. Chem. C 2013, 117, 7690–7702.

  17. Luzgin, M. V.; Rogov, V. A.; Arzumanov, S. S.; Toktarev, A. V.; Stepanov, A. G.; Parmon, V. N., Understanding Methane Aromatization on a Zn-modified High-Silica Zeolite. Angew. Chem. Int. Edit. 2008, 47, 4559–4562.

  18. Stepanov, A. G.; Arzumanov, S. S.; Gabrienko, A. A.; Parmon, V. N.; Ivanova, I. I.; Freude, D., Significant Influence of Zn on Activation of the C–H Bonds of Small Alkanes by Bronsted Acid Sites of Zeolite. ChemPhysChem 2008, 9, 2559–2563.

  19. Stepanov, A. G., Carbonylation - Heterogeneous. In Encyclopedia of Catalysis;, Horvath, I. T., Ed. Willey-Interscience, Second Edition: 2010; Vol. Vol. 2, p. 73-114.

  20. Kazantsev, M. S.; Luzgin, M. V.; Volkova, G. G.; Stepanov, A. G., Carbonylation of Dimethyl Ether on Rh/Cs2HPW12O40: Solid-State NMR Study of the Mechanism of Reaction in the Presence of a Methyl Iodide Promoter. J. Catal. 2012, 291, 9–16.

  21. Kolokolov, D. I.; Stepanov, A. G.; Jobic, H., Guest Controlled Rotational Dynamics of Terephthalate Phenylenes in Metal−Organic Framework MIL-53(AI): Effect of Different Xylene Loadings. J. Phys. Chem. C 2014, 118, 15978−15984.

  22. Gabrienko, A. A.; Arzumanov, S. S.; Luzgin, M. V.; Stepanov, A. G.; Parmon, V. N., Methane Activation on Zn2+-Exchanged ZSM-5 Zeolites. The Effect of Molecular Oxygen Addition. J. Phys. Chem. C 2015, 119, 24910–24918.

  23. Arzumanov, S. S.; Gabrienko, A. A.; Freude, D.; Stepanov, A. G., Competitive Pathways of Methane Activation on Zn2+-Modified ZSM-5 Zeolite: H/D Hydrogen Exchange with Brønsted Acid Sites versus Dissociative Adsorption to Form Zn-Methyl Species. Catal. Sci. Technol. 2016, 6, 6381–6388.

  24. Khudozhitkov, A. E.; Jobic, H.; Freude, D.; Haase, J.; Kolokolov, D. I.; Stepanov, A. G., Ultraslow Dynamics of a Framework Linker in MIL-53 (Al) as a Sensor for Different Isomers of Xylene. J. Phys. Chem. C 2016, 120, 21704-21709.

  25. Gabrienko, A. A.; Arzumanov, S. S.; Toktarev, A. V.; Danilova, I. G.; Prosvirin, I. P.; Kriventsov, V. V.; Zaikovskii, V. I.; Freude, D.; Stepanov, A. G., Different Efficiency of Zn2+ and ZnO Species for Methane Activation on Zn-Modified Zeolite. ACS Catal. 2017, 7, 1818-1830.

  26. Moreau, F.; Kolokolov, D. I.; Stepanov, A. G.; Easun, T. L.; Dailly, A.; Lewis, W.; Blake, A. J.; Nowell, H.; Lennox, M. J.; Besley, E., et al., Tailoring porosity and rotational dynamics in a series of octacarboxylate metal-organic frameworks. Proc. Natl. Acad. Sci. U. S. A. 2017, 114, 3056-3061.

  27. Khudozhitkov, A. E.; Stange, P.; Golub, B.; Paschek, D.; Stepanov, A. G.; Kolokolov, D. I.; Ludwig, R., Characterization of Doubly Ionic Hydrogen Bonds in Protic Ionic Liquids by NMR Deuteron Quadrupole Coupling Constants: Differences to H-bonds in Amides, Peptides, and Proteins. Angew. Chem.-Int. Edit. 2017, 56, 14310-14314.

  28. Yan, Y.; Kolokolov, D. I.; da Silva, I.; Stepanov, A. G.; Blake, A. J.; Dailly, A.; Manuel, P.; Tang, C. C.; Yang, S. H.; Schroder, M., Porous Metal-Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage. J. Am. Chem. Soc. 2017, 139, 13349-13360.

  29. Knebel, A.; Geppert, B.; Volgmann, K.; Kolokolov, D. I.; Stepanov, A. G.; Twiefel, J.; Heitjans, P.; Volkmer, D.; Caro, J., Defibrillation of Soft Porous Metal-Organic Frameworks with Electric Fields. Science 2017, 358, 347-351.




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